Isomerism and Stereochemistry


1003. Which of the following is different?



1004. Choose the thermodynamically most stable isomer.

Choose the thermodynamically least stable isomer.



1041.

has how many stereo centers? 0, 1, 2


1042. The selective synthesis of specific stereoisomers of epoxides can be performed using enantiomers of Jacobsen's catalyst and subtle changes in reaction conditions. Stereoisomers of phenylpropylene oxide,

, can be made this way.

 

How many stereoisomers of phenylpropylene oxide are there? 1, 2, 4

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1049. Choose the correct products for these reactions:

a.

 

A. B. C. D.

 

b.



A. B. C. D.


1050.Choose the correct products for these reactions:

a.

A. B. C. D.

 

b.

A. B. C. D.


1051. Choose the correct product for this reaction:

A. B. C. D.



1084. a. What is the R and S configuration for each stereogenic center in this sugar, from top to bottom?

 R, R, S  R, S, S  R, S, R

 

b. Is this a D or L sugar?

 

c. What is the R and S configuration for each stereogenic center in this sugar, from top to bottom?

 R, R, S  R, S, S  R, S, R

 

b. Is this a D or L sugar?


1095. How many isomers have the name bromomethylcyclopentane? (ignoring chirality)

A. 4

B. 5

C. 6

D. 7


1097. How many stereocenters (not including any N centers) are there in morphine, whose structure is shown below?

A. 4

B. 5

C. 6

D. More than 6


1098. Is the structure shown below R or S?

A. R

B. S


1099. Is the structure shown below R or S?

A. R

B. S


1100. The stereochemistry of this molecule is:

A. 1R, 3R

B. 1R, 3S

C. 1S, 3S

D. 1S, 3R


1101. Pure (S)-2-butanol has a specific rotation of +13.52 degrees. A sample of 2-butanol prepared in the lab and purified by distillation has a calculated specific rotation of +6.76 degrees. What can you conclude about the composition?

A. 50% (S), 50% impurity

B. 50% (S), 50% (R)

C. 50% (S), 50% racemic

D. some other mixture





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