JCE Software Chemistry Comes Alive!
Scattering of Blue Light and Red Light.

Blue light is scattered more efficiently than red light. This explains why skim milk and the sky are blue, but sunsets are red.

Discussion

At the beginning of this movie, the first-order images display the spectrum of the white light reflected by the screen, with the blue band closest to the center and the red farthest. (The blue and green bands on the right of the grating belong to the second order diffraction pattern.) When the container of water is moved over the aperture, there is no change in the spectrum of the transmitted light, but adding milk to the water in the container results in both striking changes to the spectrum of transmitted light and to scattering of light to the side. Before milk is added, the beam of light passing through the container is almost invisible from the side and the spectrum is that of white light; after milk is added, the beam can be seen quite clearly from the side and the intensity of the short wavelength part of the spectrum (blue and green) is much reduced in comparison to the long wavelength part (red and orange).

When the grating is removed, it is clear that red and orange are dominant colors in the unscattered light that passes through the milk suspension.

When the polarizing sheet is placed in front of the container and screen and rotated, the intensity of scattered light changes with the orientation of the polarizing sheet, but the intensity of transmitted light reflected by the screen is independent of the orientation of the polarizing sheet. (Polarization effects for the scattered light are much more obvious in the next movie, where a more dilute suspension of milk is used.) This result means that scattered light is polarized, but transmitted light is not.






Credits:
Design and Demonstration
  Jonathan Mitschele Saint Joseph’s College, Standish, ME, 04084
Video
  Jerrold J. Jacobsen University of Wisconsin - Madison, Madison, WI 53706