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Unit Cells?

  • A unit cell is a building block of a crystalline solid.

  • Shifting the unit cell along any of its edges by the length of the edge will generate identical cells to build up the entire crystal.

  • If not chosen properly, shifts of the cell will not give an identical cell (upper right unit cell).

  • Unit cells do not need to be squares or rectangles (lower right unit cell).

  • Unit cells facilitate the counting of atoms comprising the solid (empirical formula).