activity series

A Knowledge of Electrolysis Thwarts a Scam

This post describes an engaging, thought-provoking capstone activity for the Redox/Electrochemistry unit in AP Chemistry1. It may be used as a homework assignment, a collaborative in-class assignment, or as a challenging test or exam question.2 It can also be used as a hands-on and MINDS-ON laboratory activity or teacher demonstration.

 

Demonstration: Reaction of Magnesium and Silver Nitrate

I found a version of this demonstration online a couple of years ago. I admit, when I first tried it with my class it was mostly for a crowd pleaser to demonstrate the activity series of metals, but I then became very intrigued by the processes occurring. The original source only referenced the “single replacement reaction” between Mg(s) and AgNO3(aq). Therefore, when I saw a grayish product (silver) I was not surprised. However, I was surprised by the white flash and the production of a white product, which were reminiscent of the classic combustion of magnesium demonstration. This led to some research and my conclusions that follow. Read through to the end and you will find a video of the demo.