oxidation reduction

Demonstration: Reaction of Magnesium and Silver Nitrate

I found a version of this demonstration online a couple of years ago. I admit, when I first tried it with my class it was mostly for a crowd pleaser to demonstrate the activity series of metals, but I then became very intrigued by the processes occurring. The original source only referenced the “single replacement reaction” between Mg(s) and AgNO3(aq). Therefore, when I saw a grayish product (silver) I was not surprised. However, I was surprised by the white flash and the production of a white product, which were reminiscent of the classic combustion of magnesium demonstration. This led to some research and my conclusions that follow. Read through to the end and you will find a video of the demo.

Silver Plated Bulbs

I have used several different versions of the Silver Mirror or Tollen's Test lab. I am sharing the method that has proven to be the most reliable for me. The solutions should be made fresh, the directions must be followed closely and timing is very important. I like the fact that relatively small amounts of the chemicals are required, but as always you must be vigilant with safety precautions.