thermochemistry

Using My Marbles: Connecting Surface Area and Calorimetry with Temperature Curves and Thermochromic Cups

The importance of surface area can be illustrated by adding spherical solids at known sizes and temperature to other substances at different temperatures and then monitoring the rates of temperature changes of the system over time. Larger spheres (with less surface area per sample) exchanged heat with water more slowly than smaller spheres, and less thermally conductive glass spheres exchanged heat with water more slowly than iron spheres. Additional, more colorful demonstrations are described in which small glass spheres cool thermochromic plastic cups more quickly than larger glass spheres. 

Expanding on Self-Inflating Balloons: Activities Involving Moles, Gas Laws, and Thermochemistry

Balloons that inflate using carbon dioxide produced from the reaction of citric acid and sodium hydrogen carbonate can be used to demonstrate a number of aspects of chemistry. Gas laws were used with the balloons to illustrate limiting reactants, molar mass of gases, and rockets. The endothermic reaction in the balloon was visualized with an infrared camera, and the Green Chemistry aspects of these balloons were considered.

Thermal Paper as a Polarity and Acidity Detector

Thermal paper such as that used for point of sale receipts typically functions by darkening when exposed to heat. The pigment system used in this paper also darkens when exposed to solvents of intermediate polarity and acids. This enables thermal paper to be used as an inexpensive sort of indicator paper for a variety of demonstrations.